I'm looking for a fic, post-Chosen and AtS. Buffy works for the Council and Spike works for Angel. They travel around completing missions separately, and one time they finally come across each other. The keep subsequently meeting up and/or finding excuses to meet up depending on where their next mission is. Sound familiar?

That sounds like Out of This World by kittiekat: http://www.bloodshedverse.com/stories.php?go=chapters&no=4604

 That is an awesome icon afgrulerofthepen :D

Heehee, thanks! And it's sooo true! Everyone on "My Boys" list is on a TV show. Spike, of course, being one of them :D

Yep, that was the fic! Thanks!